The complexes of Co (II), Ni
(II) and Cu (II) having general formula [M (PSC)2] and [M (PTC)2],
where M = Co (II), Ni (II), Cu (II) and PSC=α-pyridone semicarbazone,
PTC=α-pyridone thiosemicarbazone been synthesized. The ligands as well as
complexes have been characterized by elemental analyses, molar conductance,
magnetic susceptibility, infrared spectra and electronic spectral data, PSC and
PTC acts as a tridentate ligand and coordination proposes through N of pyridone
ring, azomethine nitrogen and carbonyl oxygen/ thoine sulphur of
semicarbazone/thiosemicarbazone moiety. On the basis of electronic spectral and
magnetic susceptibility values the geometry of the complexes were proposed to
be octahedral. The molar conductivity values of the complexes were found to be
non-electrolytic in nature. The ligand and complexes have been screened for
their antibacterial and antifungal activities.
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