The chemistry of macro cyclic complexes has occupied a central role in the development of coordination chemistry. The metal complexes containing synthetic macro cyclic Gilligan have attracted a great deal of attention towards more biological system. They have been synthesized and characterized by UV, IR, EPR cyclic voltammetry spectral techniques. The synthesis and characterization of a series of 2-((4-methoxyphenylimino methyl)-4, 6-dichlorophenol and thiocyanate as macro cyclic mono nuclear Schiff base complexes by template method with the corresponding metal salts like Ni(II) and Cu(II).